Galvanic cell - chemical energy conversion into electrical energy Test paper Example 1: The surface of silverware gradually turns black over time. This is due to the generation of thiosilver. Some people have designed to use the principle of galvanic cell to remove it. The treatment method is: put a certain concentration of salt solution into an aluminum container, and then immerse the blackened silverware in the solution. After a period of time, the black color will fade away without losing the silver. Try to answer: In this galvanic cell reaction, the reaction at the negative electrode is ; the reaction at the positive electrode is ; the gas with the smell of rotten eggs is produced during the reaction. The total reaction equation of the galvanic cell is Analysis: According to the meaning of the question \"the black color fades without silver loss\", the change is Ag2S→Ag. Obviously, this is the positive electrode reaction of the galvanic cell: Ag2S+2e-=2Ag+S2-, and the negative electrode reaction is the oxidation reaction of the active metal: Al-3e-=Al3+. The S2- generated at the positive electrode and the Al3+ generated at the negative electrode undergo double hydrolysis in the solution: 2Al3++3S2-+6H2O=2Al(OH)3↓+3H2S↑. Answer: Al-2e-=Al3+ Ag2S+2e-=2Ag+S2- 3Ag2S+2Al+6H2O=6Ag+2Al(OH)3↓+3H2S↑ IV. Consolidation of Double Bases 1. Hydrogen-oxygen fuel cells are cells that pass H2 and O2 into the battery separately, through porous carbon electrodes immersed in 20%~40% KOH solution. The electrode reaction formula is: H2+2OH--2e-=2H2O and 1/2O2+H2O+2e-=2OH-. Which of the following statements is correct? ( ) A. The electrode that passes H2 is the positive electrode, and the electrode that passes O2 is the negative electrode B. The electrode that passes O2 is the positive electrode, and the electrode that passes H2 is the negative electrode C. After working for a period of time, the pH of the electrolyte solution increases D. The pH near the negative electrode area decreases during work 2. Put a zinc sheet and a silver sheet in contact with each other in the following solutions of the same molar concentration. After a period of reaction, the solution mass decreases ( ) A. Aluminum chloride B. Copper sulfate C. Silver nitrate D. Dilute sulfuric acid 3. In the air, steel comes into contact with salt water and electrochemical corrosion occurs. The electrode reaction occurring at the positive electrode is ( ) A. Fe-2e- Fe2+ B. 2H+2e- H¬2↑C. Na++e- Na D. 2H2O+O2+4e- 4OH-
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