This paper reviews the application and development of β2-cyclodextrin (β2CD) in analytical chemistry, including β2CD synergistic sensitization, enantiomeric resolution, β2CD-induced room temperature phosphorescence and its applications, fluorescence enhancement effect of β2CD and its derivatives, measurement of trace metals, sensors, enzyme mimics and supramolecular compounds, and research on the properties of β2CD inclusion complexes. Keywords: β2-cyclodextrin; synergistic sensitization; enantiomeric resolution; room temperature phosphorescence; fluorescence enhancement; trace metals; sensors; enzyme mimics and supramolecular compounds
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